It is widely known within the community of cosmetic
chemists that there are particular challenges when formulating products that must meet certain ‘free-of’ requirements. ‘Sulfate-free’ (EU) is no exception. While there are several classes of surfactants (EU) that are suitable replacements for sulfated products, the challenge usually occurs when an attempt is made to increase the viscosity of a sulfate-free system. This becomes even more difficult when the requirement is to maintain clarity and achieve viscosity targets without the use of polymeric thickeners (EU).
If the use of natural polymers is allowed, then the palette of available ingredients would broaden to include gums such as Xanthan gum (EU). However, if the brief is more restrictive, this is a tall order indeed! While such requirements would negate traditional and popular approaches such as the use of carbomers (EU), cellulose derivatives (EU) or highly ethoxylated materials like PEG-150 Distearate (EU), there are other avenues that are available to the formulator.
Those skilled in the art might naturally first resort to Sodium Chloride (EU) as a thickening agent – which is a cost effective approach that may deliver the desired results, depending on the salt sensitivity of the surfactant system involved. The limits for salt tolerance can easily be established by creating a salt curve with the salt contribution from surfactants included in the overall totals. Furthermore, product performance and aesthetics should also be evaluated to determine whether the rheological profile is being negatively affected to the extent that it results in stringiness.
In addition to the primary surfactants selected, the role of secondary surfactants in building viscosity should not be underestimated. Betaines (EU), Hydroxysultaines (EU), Alkanolamides (EU) and Amine Oxides (EU) are but a few of the chemical classes that have multifunctional benefits, including viscosity enhancement. Given the current status of mono- and diethanolamines, mono- and diisopropanolamines have proven to be effective substitutes as foam boosters (EU) and viscosifiers. These chemical classes are well represented among products listed on ULProspector.com. These types of ingredients, in conjunction with Sodium Chloride, may also benefit non-ionic systems, which can be stubbornly non-responsive to salt.
Surfactant ratios also play a significant role is maximizing viscosity and should be thoroughly investigated. Understandably, given aggressive timelines, time is not always a luxury that the formulator can afford. Employing an experimental design as a tool to identify optimal ratios should be a consideration whenever possible. Similarly, the order in which surfactants are added can also impact viscosity and should be investigated as well as the system’s response to pH adjustment.
While development of clear sulfate-free shampoos and shower gels without polymeric thickeners may at first seem to be a daunting task, be assured that there are several formulation and ingredient options available that would allow you to demonstrate your creative talents.
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10 Responses to “Tackling the Clear, Sulfate-Free Formulation Challenge”
Pricilla, perhaps you remember me from ISP days. I was interested in reading your article, but it seems that just the introduction was available on the ULProspector. Will there be further articles by you on this sulfate free thickening subject? [email protected]
Excellent article. Thanks Priscilla. Do you have a suggestion for thichening APG’s like Decyl Glucoside.
I have a 50% solution of a commercial Decy Glucoside (50% active) and would like to increase the viscosity to about 8000 cps.
We are shampoos manufacturers in Puerto Rico and will like to have a contact to help us in the formulations. Please let me know who should we contact for advisement.
Two of our personal care contributing authors offer consulting services. Please see their bios on the Knowledge Center for more information:
Arun Nandagiri https://knowledge.ulprospector.com/author/arun-nandagiri/
George Deckner https://knowledge.ulprospector.com/author/george-deckner/
This article was in response to a member’s question, received through the member survey, regarding options for thickening sulfate-free systems without polymeric thickeners. While additional articles on the broader topic of ‘sulfate-free’ are not currently planned, I will add this to our list for future topics. Thank you for your interest!
What type of Product Formulations are you seeking assistance with?
For clear sulfate free systems, the ISELUX technology from Innsospec is a great option, as well as performance blends such as the Iselux SFS and Iselux Ultra Mild, which are cold process compatible and easily thickened with a wide viscosity range. Innospec offers great insight and support in formulating with these technologies with superb application support and demonstration samples. Definitely worth checking out!
Thank you Ms Taylor – Nice starting discussion you have left us thirsting for more. – President National Society of Cosmetic Chemists
Excellent article Priscilla.
What primary surfactants would you suggest to increase the viscosity of a sulfate-free system when the requirement is to maintain clarity in the final formulation?
please i need a suitable formula for a sulphate free shampoo with Crodasinic LS30 and Carbopol Utrez 21 as viscosity builder with high clarity. i appreciate.