
The general topic of natural ingredients in cosmetics has been extensively covered in industry literature and forums, as well as various Knowledge Center articles.
If the questions submitted by Prospector members are any indication, the level of interest in the broader topic of “naturals” and the subtopic of natural preservatives in cosmetics remains high. Although natural preservatives were thoroughly discussed in “Natural Preservatives and Colorants,” the present article aims to address some lingering questions on balancing support of a natural concept with efficacy and affordability.
Supporting a Natural Concept
First and foremost, what is the definition of “natural” within personal care? Several authors have addressed this question but the definition offered in “The Challenge of Natural Cosmetics” is worth restating:
Perhaps the biggest challenge is to figure out what your company considers ‘natural.’ There is no single definition and the number of different standards out there is overwhelming. As a formulator, you’ll want to get specific direction on exactly which ingredients you’re allowed to use and which to avoid. If your company doesn’t know, then you should just choose one of the leading natural cosmetic standards and stick with it.”
Getting specific direction from your company or customer cannot be over emphasized as there are varying perceptions among consumers about what makes a product “natural.” Most common is the belief that a “natural” ingredient must be recognizable and not sound “chemical” – which is a viewpoint that your marketing team may want to promote to enhance consumer appeal.
To meet this objective, a formulator can consider products that have been developed as alternatives to synthetic preservatives. Examples of products positioned as “natural” or naturally-derived preservatives include:
- Neopein® by Bio-Botanica:
- INCI Name: Origanum Vulgare Extract (and) Thymus Vulgaris (Thyme) Extract (and) Olea Europaea (Olive) Leaf Extract (and) Rosmarinus Officinalis (Rosemary) Leaf Extract (and) Lavandula Angustifolia (Lavender) Flower Extract (and) Hydrastis Canadensis (Goldenseal) Root Extract
- Sharon Biomix Free II Liquid by Acme Hardesty Co.:
- INCI Name: Phenylpropanol (and) Glycerin (and) Citrus Aurantium Amara (Bitter Orange) Fruit Extract (and) Citrus Reticulata (Tangerine) Fruit Extract (and) Citrus Aurantium Sinensis Peel Extract (and) Ascorbic Acid (and) Lactic Acid (and) Citric Acid (and) Aqua
- MicroCurb™ OC by Kemin:
- INCI Name: Caprylic Acid (and) Origanum Vulgare Leaf Extract
- Natural Preservier™ by Premier Specialities:
- INCI Name: Water (and) Gluconic Acid (and) Sodium Benzoate
Efficacy
The concern among formulators regarding the effectiveness of natural preservatives in cosmetics is understandable, given their relatively short history of use and body of efficacy data as compared to that available for traditional preservatives. Whether it is natural or synthetic, the basic function of any preservative is to prevent or retard microbial growth in the finished product. As such, ensuring that a product is well preserved is a critical aspect of formula development.
Minimum inhibitory concentration (MIC) data are usually provided by suppliers and should be carefully reviewed when considering a preservative. While this information can be useful, preservation efficacy testing on the formula being considered for launch would provide the formulator with an understanding of the product’s microbiological integrity.
Affordability
A formulator is often tasked with delivering a product to meet all development objectives within a given budget. While this sometimes could be the most challenging aspect of the development process, the temptation to curtail costs by using less than optimum levels of preservatives should be avoided – for reasons outlined above. If natural preservatives are required to support the overall product concept, but are found to negatively impact cost, and negotiations with the supplier were not fruitful, then further discussions with marketing or the customer may be warranted to establish more realistic cost targets.
Identifying a preservative system that would support a natural product concept might present a challenge but should not necessarily be considered an impossible task. Healthy relationships with suppliers, maintaining an awareness of cross-category technology developments (primarily food and personal care) and keeping an open mind to innovation, can often help illuminate a path to success.
For further reading on natural cosmetics, see:
- The Challenge of Natural Cosmetics
- Formulating with Natural Surfactants
- Natural Preservatives and Colorants
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Thank you Priscilla!
Thanks a lot
Dear Priscilla,
with the much broader consensus regarding the term “natural” in Europe there is also a common understanding what has to be considered as “natural preservation”. All natural preservation systems have in common that they are not made from fossil carbon source. They may either be extracted from natural (vegetable) sources or made from naturally derived building blocks by simple chemical conversions. In the past 20 years a large number of scientific publications has been published providing at least in parts information regarding reliable preservation options for natural and organic personal care products in addition to the petrochemically derived preservatives permitted by the most accepted natural and organic cosmetic standards. For those being interested in the topic here is a list in chronological order:
Petersen, W. Antimicrobial ingredients for self-preserving cosmetics. Euro Cosmetics, 1999, Feb, 28-36.
Jaenichen, J.; Johnson, C.H. Keeping the balance. Soap Perfumery & Cosmetics, 2005, Sept, 81-90.
Ibarra, F.; Johnson, C.H. Natural preservation from concepts in nature. Cosmetics & Toiletries, 2008, March, 81-90.
Ibarra, F. Effective preservation with multifunctional naturals. Personal Care, 2008, Sept, 86-88.
A. Varvaresou, A.; Papageorgiou S.; Tsirivas, E.; Protopapa E.; Kintziou H.; Kefala V.; Demetzos C. Self-preserving cosmetics. Int. J. Cosm. Sci., 2009 (31) 163–175.
Ibarra, F. Effective Preservation with Natural Multifunctional Ingredients. Happi, 2012.
Thiemann, A.; Jänichen, J. The Formulator’s Guide to Safe Cosmetic Preservation. Personal Care Europe, 2014, Nov, 39-43.
Thiemann, A.; Petersen, W. Emulsifier system influences O/W emulsion preservation. Personal Care Europe, 2016, Feb, 60-62.
Best regards
Do all of the Natural Preservatives listed above work at a ph below 6.00 ?
Could you recommend any that will work above a ph of 7.00.
Priscilla
The one main issue that you are not discussing and is always a concern for the microbiologist is stability and long term efficacy. As these molecules that you are recommending may do well in a 28 day challenge test in a very simple water in oil emulsion the long term stability of these compounds needs to be guaranteed and documented.
The second concern is that MIC values are great as initial screening tools but once the material goes into a cosmetic emulsion matrix all of those values go out the window.
A third point is with us using more exotic raw materials such as silicones, film formers and wetting agents these natural preservatives do not always work in these systems. I would not consider them broad spectrum but are very limited in their application due to odor, compatibility, etc..
Thank you Pricilla for sharing this valuble information natural preservation.
Cynthia
Thank you Priscilla.
I would ask folks to also look at Aminat G. This is a cationic ingredient but one of the natural preservatives that many of our customers are looking at.
I also agree with Steve that all formulations and potential ingredients should be challenged tested and documented.
We have found that combinations are necessary to pass OTC challenge test in most cases Dr Bob