Flexibility is an important mechanical property of coatings. Insufficient flexibility can have several causes, and it can create a range of problems. This article focuses on the most common causes and possible consequences of internal stress. Also, some methods to prevent stress in coatings are discussed.
During film formation, a liquid paint transforms into a solid coating. Two processes that can take place during film formation play a crucial role in many systems.
First, evaporation of volatile components, like organic solvents or water, can occur. A film shrinks when material leaves the system because of evaporation. Secondly, a chemical reaction of resin and crosslinker, called crosslinking, takes place in many systems. Preferably, shrinkage only occurs in the direction perpendicular to the paint-air interface.
Causes of stress
Several phenomena can result in stress building up in the coating. First, the adjustment of evaporation and crosslinking might not be optimum. Consider a system in which crosslinking is fast and evaporation is slow. In such a system, a gel is formed when there is still a considerable amount of solvent present in the film. When evaporation continues, the voids that appear when solvent molecules leave the film, will be filled with the binder system. Stress can build up when the binder system has limited mobility caused by the high crosslink density.
In solvent-free, UV-curing systems, the binder matrix contracts because of reaction shrinkage. Even though the system does hardly loose material because of evaporation, stress can build up in the binder matrix during film formation.
A low amount of binder material is present in systems that have a high loading of solid particles. The demands, with respect to flexibility, of the binder system goes up when the percentage of solid particles increases.
Stress can evolve in a coating when the dimensions of the substrate change because of fluctuations in temperature and/or humidity or under the influence of mechanical force.
In general, it can be said that internal stress will build up when relaxation of the binder system is insufficient to cope with the changes that take place in the system.
Possible problems caused by stress
A variety of undesired phenomena can take place when internal stress builds up during film formation. Cracking of the coating occurs when the strength of the film is insufficient to cope with the stress.
A coating can break at sharp edges of the substrate. Also, the coating can be pulled loose from the substrate. This loss of adhesion is often called delamination.
Determination of stress
It is often difficult to determine whether or not stress builds up in a coating. In a simple test, a system is applied onto a flexible inert substrate. The system will curl when stress builds up during film formation.
In most coatings, internal stress expresses itself via film defects as mentioned above: cracking, breakage and/or loss of adhesion.
The most important attention points, with respect to the prevention of stress, are the binder system and the quality of film formation. In systems in which both evaporation and crosslinking takes place, the two processes must be adjusted to each other. Stress in systems in which reaction shrinkage occurs can be prevented by using reactive flexibilisers in the system. Finally, in systems with high particle loading, stress can be reduced by using a more flexible binder system or by optimising film formation.
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6 Responses to “Stress in Coatings”
A very informative article.
Good article. Dr.Beetsma can you let me know whether castor oil glycidyl ether can improve the flexibility of coatings based on epoxy resins
This depends on the composition of the system. But in principle this is the cause. Explanation is that castor oil is a flexible molecule that can behave as flexibiliser. The pre-condition is that the castor oil derivative is compatible with the epoxy system.
first a small remark, Subhash is talking about castor oil glycidyl ether, which means it will react with the amine cure and form a solid part of the coating.
I agree with Jochum that Castor oil as is will be a flexibiliser (if it mixes both in the base coat and in the set especially if the paint is solvent based and the solvent has disappeared). The second is the effect of the glycidyl ether. It is a mono functional epoxy and as such it is called a chain stopper. The Ep-Am-Ep-Am-Ep cannot grow from this point on. This is good for not building up more stress, but, depending of the use of the paint, hardness will be less and protection aginst long term exposure to chemicals will be less. How much less is something you have to test for. No need to be afraid that suddenly your coating fals apart due to some monofunctional epoxy, but it is a point to consider and test for.
Many good articles. Keep on writing.
Good solid article for new chemists seeing some of these issues for the first time or seasoned veterans who may need a reminder.
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